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Chemistry Question on de broglie hypothesis

The de-Broglie's wavelength of an electron in the 4th4^{\text{th}} orbit is ______ πa0\pi a_0. (a0=Bohr’s radiusa_0 = \text{Bohr's radius})

Answer

The condition for the de-Broglie wavelength of an electron in an orbit is given by:

2πrn=nλd2 \pi r_n = n \lambda_d

where rnr_n is the radius of the nn-th orbit, nn is the principal quantum number, and λd\lambda_d is the de-Broglie wavelength.

The radius of the nn-th orbit in the Bohr model is given by:

rn=2πa0n2Zr_n = 2 \pi a_0 \frac{n^2}{Z}

Substituting this into the equation:

2πa0n2Z=nλd2 \pi a_0 \frac{n^2}{Z} = n \lambda_d

For an electron in the 4th orbit and for a hydrogen atom (Z=1Z = 1):

2πa0421=4λd2 \pi a_0 \frac{4^2}{1} = 4 \lambda_d

Simplifying:

λd=8πa0\lambda_d = 8 \pi a_0

Hence, the de-Broglie's wavelength of the electron in the 4th orbit is 8πa08 \pi a_0.