Question
Chemistry Question on de broglie hypothesis
The de-Broglie's wavelength of an electron in the 4th orbit is ______ πa0. (a0=Bohr’s radius)
Answer
The condition for the de-Broglie wavelength of an electron in an orbit is given by:
2πrn=nλd
where rn is the radius of the n-th orbit, n is the principal quantum number, and λd is the de-Broglie wavelength.
The radius of the n-th orbit in the Bohr model is given by:
rn=2πa0Zn2
Substituting this into the equation:
2πa0Zn2=nλd
For an electron in the 4th orbit and for a hydrogen atom (Z=1):
2πa0142=4λd
Simplifying:
λd=8πa0
Hence, the de-Broglie's wavelength of the electron in the 4th orbit is 8πa0.