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Question

Chemistry Question on General Principles and Processes of Isolation of Elements

The cyanide process of gold extraction involves leaching out gold from its ore with CNCN^- in the presence of Q in water to form R. Subsequently, R is treated with T to obtain Au and Z. Choose the correct option(s)

A

Q is O2_2

B

T is Zn

C

Z is [Zn(CN)4]2[Zn(CN)_4]^{2-}

D

R is [Au(CN)4][Au(CN)_4]^-

Answer

Z is [Zn(CN)4]2[Zn(CN)_4]^{2-}

Explanation

Solution

4Au(s)+8CN(aq)+2H2O(aq)+{4Au(s) + 8CN^{-}(aq) + 2H2O(aq) +} O2(g)(Q)\underset{\text{(Q)}}{{O2(g)}} >4[Au(CN)2](aq)+4OH(aq){->4[Au(CN)2]^{-}(aq) + 4OH^{-}(aq)}
2[Au(CN)2](R)\underset{\text{(R)}}{{2[Au(CN)2]^{-}}} (aq)+{(aq) +} Zn(s)(T)\underset{\text{(T)}}{{Zn(s)}} >[Zn(CN)4]2(Z)\underset{\text{(Z)}}{{{->}{[Zn (CN)4]^{2-}}}} (aq)+2Au(s){(aq) + 2Au(s)}