Question
Chemistry Question on Group 13 Elements
The correct statement among the following is
A
(SiH3)3N is pyramidal and more basic than (CH3)3N
B
(SiH3)3N is planar and more basic than (CH3)3N
C
(SiH3)3N is pyramidal and less basic than (CH3)3N
D
(SiH3)3N is planar and less basic than (CH3)3N
Answer
(SiH3)3N is planar and less basic than (CH3)3N
Explanation
Solution
nitrogen is sp3 hybrid and pyramidal no back-bonding i.e.more basic
Nitrogen sp2 hybrid and planar due to back bonding and less basic because lone pair is not available for donation.