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Question

Chemistry Question on Group 13 Elements

The correct statement among the following is

A

(SiH3)3N{(SiH3)3N} is pyramidal and more basic than (CH3)3N{(CH3)3N}

B

(SiH3)3N{(SiH3)3N} is planar and more basic than (CH3)3N{(CH3)3N}

C

(SiH3)3N{(SiH3)3N} is pyramidal and less basic than (CH3)3N{(CH3)3N}

D

(SiH3)3N{(SiH3)3N} is planar and less basic than (CH3)3N{(CH3)3N}

Answer

(SiH3)3N{(SiH3)3N} is planar and less basic than (CH3)3N{(CH3)3N}

Explanation

Solution

nitrogen is sp3sp^3 hybrid and pyramidal no back-bonding i.e.more basic
Nitrogen sp2sp^2 hybrid and planar due to back bonding and less basic because lone pair is not available for donation.