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Question

Chemistry Question on Amines

The correct stability order of the following diazonium salt iscorrect stability order of the diazonium salt

A

(A) > (B) > (C) > (D)

B

(A) > (C) > (D) > (B)

C

(C) > (A) > (D) > (B)

D

(C) > (D) > (B) > (A)

Answer

(A) > (C) > (D) > (B)

Explanation

Solution

Diazonium salt containing aryl group directly linked to electron donating group is the most stable due to resonance. The +M effect stabilizes the intermediate, whereas Electron withdrawing group on benzene destabilizes the intermediate at the para position.
Order will be A > C > D > B.

Diazonium salt reaction mechanism

So, the correct option is (B): (A) > (C) > (D) > (B).