Solveeit Logo

Question

Question: The correct sequence of bond length in a single bond, a double bond and triple bond of \(C\) is: A...

The correct sequence of bond length in a single bond, a double bond and triple bond of CC is:
A:
B:
C:
D:

Explanation

Solution

Bond length is the average distance between the nuclei of two bonded atoms. Bond length is different for different bonding atoms. Bond length is related to bond order, bond strength and bond dissociation energy. It depends upon the number of bonds between two atoms as well.

Complete step by step answer:
Bond length is the average distance between the nuclei of two bonded atoms. This length mainly depends on bond order. Bond order is calculated by dividing the number of bonds with total number of bonding pairs. In CCC - C there is one bond and one bonding pair. This means bond order of CCC - C is 11. Similarly in There are two bonds and one bonding pair. So, bond order of this molecule is 22 (as bond order isnumber of bondstotal bonding pairs\dfrac{{{\text{number of bonds}}}}{{{\text{total bonding pairs}}}} ). In There are three bonds and one bonding pair therefore the bond order of this molecule is 33. Bond length is inversely proportional to bond order. This means more is the bond order less is the bond length or less is the bond order more is the bond length. Bond order of triple bond CC is maximum therefore bond length of triple bond carbon is minimum and bond order of single bond carbon is minimum this means bond length of single bond carbon will be maximum. This means correct order of bond length will be:

So, correct answer is option A.

Note:
Bond angle is the angle which is formed between two bonds. For the formation of bond angle there must be at least three atoms and two bonds between these atoms. Just like bond length, bond angle is also different for different molecules. It depends upon electronegativity, geometry and lone pairs on that molecule.