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Question

Question: The correct order of the decreasing pK\textsubscript{a} values of the compounds is ...

The correct order of the decreasing pK\textsubscript{a} values of the compounds is

A

I>II>III>IV

B

II>I>III>IV

Answer

II > I > III > IV

Explanation

Solution

The pKa values are approximately:

  • Methanol (II): pKa ≈ 16

  • Phenol (I): pKa ≈ 10

  • Benzoic acid (III): pKa ≈ 4.2

  • Formic acid (IV): pKa ≈ 3.75

Since a lower pKa indicates a stronger acid, the order from the highest pKa (weak acid) to the lowest pKa (strong acid) is: Methanol (II) > Phenol (I) > Benzoic acid (III) > Formic acid (IV)