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Question

Chemistry Question on The solid state

The contribution of particle at the edge centre to a particular unit cell is.

A

12\frac{1}{2}

B

14\frac{1}{4}

C

1

D

18\frac{1}{8}

Answer

14\frac{1}{4}

Explanation

Solution

An atom at the edge centre is shared by four unit cells in the lattice and hence, contributes only 14\frac{1}{4} th to a particular unit cell Also, there are 12 edge centres in a unit cell. Thus, total number of atoms at the edge centres per unit cell. 12×143-12 \times \frac{1}{4}-3