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Question

Chemistry Question on Chemical Reactions

The compounds formed at anode in the electrolysis of an aqueous solution of potassium acetate are

A

CH4CH_4 and H2H_2

B

CH4CH_4 and CO2CO_2

C

C2H6C_2H_6 and CO2CO_2

D

C2H4C_2H_4 and Cl2Cl_2

Answer

C2H6C_2H_6 and CO2CO_2

Explanation

Solution

It is a Kolbe?? synthesis CH3COOK<=>CH3COO+K+CH_{3}COOK {<=>} CH_{3}COO^{-}+K^{+} At anode : 2CH3COOCH3CH3CH3+2CO2+2e2CH_{3}COO^{-} \to CH_{3}-CH_{3}-CH_{3}+2CO_{2}+2e^{-} At cathode : 2K++2e2K>[2H2O]2KOH+H22K^{+}+2e^{-} \to 2K { ->[2H_{2}O] }2KOH+H_{2}