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Question

Chemistry Question on coordination compounds

The charge on the central metal ion in the complex [Ni(CO)4][Ni(CO)_4] is

A

2

B

4

C

0

D

3

Answer

0

Explanation

Solution

Let in [Ni(C0)4][Ni(C0)_4], oxidation state (charge) of Ni is x.
Ni(CO)4\, \, \, \, \, \, \, \, \, \, \, \, \, Ni(CO)_4
x+(0×4)=0[\, \, \, \, \, \, \, \, \, \, \, x + (0 \times 4) = 0 [\because Oxidation state of CO= O]
\therefore\, \, \, \, \, \, \, \, \, \, \, \, \, \, \, x=0
In metal carbonyl, oxidation state of metal is always zero.