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Question

Chemistry Question on General Principles and Processes of Isolation of Elements

The carbon-based reduction method is not used for the extraction of

A

tin from SnO2SnO_2

B

iron from Fe2O3Fe_2O_3

C

aluminium from Al2O3Al_2O_3

D

magnesium from MgCO3.CaCO3MgCO_3 . CaCO_3

Answer

magnesium from MgCO3.CaCO3MgCO_3 . CaCO_3

Explanation

Solution

Al has greater affinity for oxygen, hence oxide is not reduced by carbon. MgO and CaO (formed in the calcination from carbonates) are stable species and not reduced by carbon.
During Smelting SnO2+C21300CSn+COSnO_2+C_2\xrightarrow{1300^{\circ}C}Sn+CO
2Fe2O3+3CΔ4Fe+3CO22Fe_2O_3+3C\xrightarrow{\Delta}4Fe+3CO_2