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Question

Chemistry Question on properties of d block elements

The calculated spin only magnetic moment of Cr2+Cr^{2+} ion is :

A

3.87 BM

B

4.90 BM

C

5.92 BM

D

2.84 BM

Answer

4.90 BM

Explanation

Solution

Electronic configuration of Cr=[Ar]3d54s1Cr=[Ar]3d^{5}\,4s^{1}
Electronic configuration of Cr+2=[Ar]3d4Cr^{+2}=[Ar]3d^{4}
Number of unpaired electrons =4= 4
Spin only magnetic moment =n(n+2)BM=\sqrt{n\left(n+2\right)}BM as n=4n=4
μ=4(4+2)\therefore\mu=\sqrt{4\left(4+2\right)}
=24=\sqrt{24}
=4.90BM=4.90\,BM