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Question

Chemistry Question on Bond Parameters

The bond angles of NH3,NH1+NH _{3}, NH _{1}^{+}and NH2NH _{2}^{-}are in the order

A

NH2>NH3>NH4+NH^{-}_2 > NH_3 > NH^+_4

B

NH4+>NH3>NH2NH^+_4 > NH_3 > NH^{-}_2

C

NH3>NH2>NH4+NH_3 > NH^{-}_2 > NH^+_4

D

NH>NH4+>NH2NH > NH^+_4 > NH^{-}_2

Answer

NH4+>NH3>NH2NH^+_4 > NH_3 > NH^{-}_2

Explanation

Solution

As the number of lone pairs of electrons increases, bond angle decreases. Thus, the order of bond angle is
NH4+(no/p)>NH3(1/p)>NH2(2/p)\underset{( no / p )}{NH _{4}^{+}} > \underset{(1 / p )}{NH _{3}} > \underset{(2 / p )}{NH _{2}^{-}}