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Question: The average translational kinetic energy and the rms speed of molecules in a sample of oxygen at 300...

The average translational kinetic energy and the rms speed of molecules in a sample of oxygen at 300K are 6.21 x 10-21J and 484 m/s respectively. The corresponding values at 600K area nearly (assuming ideal gas behavior).

A

12.42 x 10-21J, 968 m/s.

B

6.21 x 10-21J, 968 m/s

C

8.78 x 10-21J, 684m/s

D

12.42 x 10-21J, 684 m/s

Answer

12.42 x 10-21J, 684 m/s

Explanation

Solution

KE=32KTKE = \frac{3}{2}KT,
νrms=3RTM\nu_{rms} = \sqrt{\frac{3RT}{M}}

i.e. KE2KE1=T2T1=2\frac{KE_{2}}{KE_{1}} = \frac{T_{2}}{T_{1}} = 2

\therefore KE2=2KE1=2x6.21x1021KE_{2} = 2KE_{1} = 2x6.21x10^{- 21}

Vrms,2Vrms,1=T2T1=2\frac{V_{rms,2}}{V_{rms,1}} = \sqrt{\frac{T_{2}}{T_{1}} = \sqrt{2}}

\therefore Vrms,2=2xVrms,1V_{rms,2} = \sqrt{2}xV_{rms,1} = 684 m/s.