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Question: The average translational energy and the rms speed of molecules in a sample of oxygen at 300K are 6....

The average translational energy and the rms speed of molecules in a sample of oxygen at 300K are 6.21 x 10-21J and 484 m/s respectively. The corresponding values at 600K are nearly (assuming ideal gas behavior).

A

12.42 x 10-21J, 968 m/s.

B

6.21 x 10-21J, 968 m/s

C

8.78 x 10-21J, 684m/s

D

12.42 x 10-21J, 684 m/s

Answer

12.42 x 10-21J, 684 m/s

Explanation

Solution

KE=32KT\mathrm { KE } = \frac { 3 } { 2 } \mathrm { KT },

i.e.

\therefore KE2=2KE1=2×6.21×1021\mathrm { KE } _ { 2 } = 2 \mathrm { KE } _ { 1 } = 2 \times 6.21 \times 10 ^ { - 21 } = 12.42 × 10-21J

Vrms,2 Vrms,1=T2 T1\frac { \mathrm { V } _ { \mathrm { rms } , 2 } } { \mathrm {~V} _ { \mathrm { rms } , 1 } } = \sqrt { \frac { \mathrm { T } _ { 2 } } { \mathrm {~T} _ { 1 } } } = √2

\therefore
= 684 m/s.

Hence (4) is correct