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Question

Chemistry Question on p -Block Elements

The aqueous solution/liquid that absorbs nitric oxide to a considerable extent is:

A

lead nitrate

B

nitric acid

C

ferrous sulphate

D

sodium hydroxide

Answer

ferrous sulphate

Explanation

Solution

The aqueous solution/liquid of ferrous sulphate (FeSO4)(FeS{{O}_{4}}) absorbs nitric oxide to a considerable extent to give brown coloured
FeSO4.NOFeS{{O}_{4}}.NO .
This is the ring test for identifying the
NO3NO_{3}^{-} radical. FeSO4+NOFeSO4NObrownringFeS{{O}_{4}}+NO\xrightarrow{{}}\underset{brown\,ring}{\mathop{FeS{{O}_{4}}NO}}\,
(6FeSO4+2HNO3+2H2SO4(6FeS{{O}_{4}}+2HN{{O}_{3}}+2{{H}_{2}}S{{O}_{4}}\xrightarrow{{}} 3Fe2(SO4)3+4H2O+2NO)3F{{e}_{2}}{{(S{{O}_{4}})}_{3}}+4{{H}_{2}}O+2NO\uparrow )