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Question

Physics Question on Laws of thermodynamics

The absolute enthalpy of neutralisation of the reaction MgO(s)+2HCl(aq)MgCl2(aq)+H2O(l)MgO (s)+2 HCl (a q) \longrightarrow MgCl _{2}(a q)+ H _{2} O (l) will be

A

less than 57.33kJmol1-57.33 \,kJ \,mol ^{-1}

B

57.33kJmol1-57.33 \,kJ \,mol ^{-1}

C

greater than 57.33kJmol1-57.33\, kJ\, mol ^{-1}

D

57.33kJmol157.33\, kJ\, mol ^{-1}

Answer

less than 57.33kJmol1-57.33 \,kJ \,mol ^{-1}

Explanation

Solution

Heat of neutralisation of strong acid and strong base is 57.33kJ.MgO-57.33\, kJ . MgO is weak base while HCIHCI is strong acid, so the heat of neutralisation of MgOMgO and HCIHCI is lower to 57.33kJ-57.33\, kJ because MgOMgO requires some heat in ionisation, then net released amount of heat is decreased.