Question
Question: \[\text{SO}_{2}\] reduces \[\text{Cr}_{2}\text{O}_{7}^{2-}\]\( to \)\[\text{Cr}^{2+}\] . The change ...
SO2 reduces \text{Cr}_{2}\text{O}_{7}^{2-}$$$ to $$$\text{Cr}^{2+} . The change in oxidation number of Cr is:
Solution
We can see that it is given in the reduction of Cr2O72− takes place due to the presence of SO2 and leads to the formation of Cr2+ . Therefore, we can say that in this reaction, SO2 act as a reducing agent.
Complete step by step answer:
We can assume that the oxidation number of Cr in Cr2O72− be x. The value of x is calculated as shown below.
2x+7(−2)=−2
x =2−2+14
=+6
We can say that in the case of Cr2+ the oxidation number of Cr in Cr2+ is equal to the charge on Cr atom that is +2.
We can write the reduction reaction in which tCr2O72− reduces to Cr2+ can be written as follows.
Cr2O72−→2Cr2+
We can see that in the above reaction the change in the oxidation number per Cr atom is −4. Thus we can conclude that the oxidation number of Cr decreases by four.
Note:
We know that the decrease in the oxidation number of species in a redox reaction is regarded as reduction. However, the increase in the oxidation number is considered as oxidation.