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Question: \[\text{SO}_{2}\] reduces \[\text{Cr}_{2}\text{O}_{7}^{2-}\]\( to \)\[\text{Cr}^{2+}\] . The change ...

SO2\text{SO}_{2} reduces \text{Cr}_{2}\text{O}_{7}^{2-}$$$ to $$$\text{Cr}^{2+} . The change in oxidation number of Cr\text{Cr} is:

Explanation

Solution

We can see that it is given in the reduction of Cr2O72\text{Cr}_{2}\text{O}_{7}^{2-} takes place due to the presence of SO2\text{SO}_{2} and leads to the formation of Cr2+\text{Cr}^{2+} . Therefore, we can say that in this reaction, SO2\text{SO}_{2} act as a reducing agent.

Complete step by step answer:
We can assume that the oxidation number of Cr\text{Cr} in Cr2O72\text{Cr}_{2}\text{O}_{7}^{2-} be xx. The value of xx is calculated as shown below.
2x+7(2)=22 x+7(-2) =-2
x =2+142\dfrac{-2+14}{2}
=+6
We can say that in the case of Cr2+{Cr}^{2+} the oxidation number of Cr{Cr} in Cr2+Cr^{2+} is equal to the charge on Cr{Cr} atom that is +2+2.
We can write the reduction reaction in which tCr2O72t{Cr}_{2}{O}_{7}^{2-} reduces to Cr2+{Cr}^{2+} can be written as follows.
Cr2O722Cr2+\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-} \rightarrow 2 \mathrm{Cr}^{2+}
We can see that in the above reaction the change in the oxidation number per Cr\text{Cr} atom is 4-4. Thus we can conclude that the oxidation number of Cr\text{Cr} decreases by four.

Note:
We know that the decrease in the oxidation number of species in a redox reaction is regarded as reduction. However, the increase in the oxidation number is considered as oxidation.