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Question

Chemistry Question on Stoichiometry and Stoichiometric Calculations

CH3COCl\text{C}{{\text{H}}_{\text{3}}}\text{COCl} does not react with:

A

diethyl ether

B

phenol

C

ethanol

D

aniline

Answer

phenol

Explanation

Solution

C2H5OC2H5+CH3COClZnCl2{{C}_{2}}{{H}_{5}}O{{C}_{2}}{{H}_{5}}+C{{H}_{3}}\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,Cl\xrightarrow{ZnC{{l}_{2}}} C2H5Cl+CH3COOC2H5{{C}_{2}}{{H}_{5}}Cl+C{{H}_{3}}COO{{C}_{2}}{{H}_{5}}
CH3COOC2H5+HClC{{H}_{3}}COO{{C}_{2}}{{H}_{5}}+HCl
Aceryl chloride does not react direct with phenol. Firstly phenol reacts with alkali to form sodium phenoxide which reacts with acetyl, chloride to give phenyl acetate.