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Question: Taking Rydberg’s constant \(R_{H} = 1.097 \times 10^{7}m\) first and second wavelength of Balmer ser...

Taking Rydberg’s constant RH=1.097×107mR_{H} = 1.097 \times 10^{7}m first and second wavelength of Balmer series in hydrogen spectrum is.

A

2000 Å, 3000 Å

B

1575 Å, 2960 Å

C

6529 Å, 4280 Å

D

6552 Å, 4863 Å

Answer

6552 Å, 4863 Å

Explanation

Solution

1λ=R[1n121n22].\frac{1}{\lambda} = R\left\lbrack \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right\rbrack. For first wavelength, n1=2n_{1} = 2, n2=3n_{2} = 3λ1=6563A˚\lambda_{1} = 6563Å. For second wavelength, n1=2n_{1} = 2, n2=4n_{2} = 4

λ2=4861A˚\lambda_{2} = 4861Å