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Question

Chemistry Question on Unit Cells

Suppose the mass of a single Ag-atom is mm. Ag metal crystallises in fcc lattice with unit cell of length aa. The density of AgAg metal in terms of aa and mm is

A

4ma3\frac{4m}{a^{3}}

B

2ma3\frac{2m}{a^{3}}

C

ma3\frac{m}{a^{3}}

D

m4a3\frac{m}{4a^{3}}

Answer

4ma3\frac{4m}{a^{3}}

Explanation

Solution

Given that,
Mass of single Ag-atom =m=m
Unit cell length =a=a
Total atoms present per unit cell of fcc lattice =4=4
Therefore, mass of unit cell becomes 4m4 m.
Volume of unit cell =a3=a^{3}
Density( ρ)= Mass of unit cell  Volume of unit cell \rho)=\frac{\text { Mass of unit cell }}{\text { Volume of unit cell }}
=4ma3=\frac{4 m}{a^{3}}