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Question

Chemistry Question on Ideal gas equation

Suppose ideal gas equation follows VP3=VP^3 = constant. Initial temperature and volume of gas are T and V respectively. If gas expands to 27V, then its temperature will become

A

TT

B

9T9T

C

27T27T

D

T9\frac{T}{9}

Answer

9T9T

Explanation

Solution

Given: VP3=VP^3 = constant =k= k or P=kV1/3P = \frac{k}{V^{1/3}} According to ideal gas equation, PV=nRTPV = nRT kV1/3V=nRT\therefore \frac{k}{V^{1/3}} V = nRT or V2/3=nTRkV^{2/3} = \frac{nTR}{k} Hence, (V1V2)2/3=T1T2\left(\frac{V_{1}}{V_{2}}\right)^{2/3} = \frac{T_{1}}{T_{2}} [V27V]2/3=T1T2\left[\frac{V}{27V}\right]^{2/3} = \frac{T_{1}}{T_{2}} or T2=9T1=9TT_{2} = 9\,T_{1} = 9T