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Question

Chemistry Question on Alcohols, Phenols and Ethers

Statement I: The acidic strength of monosubstituted nitrophenol is higher than phenol because of electron withdrawing nitro group.
Statement II: o-nitrophenol, m-nitrophenol and p-nitrophenol will have same acidic strength as they have one nitro group attached to the phenolic ring.
Choose the most appropriate answer from the options given below:

A

Both Statement I and Statement II are correct.

B

Both Statement I and Statement II are incorrect.

C

Statement I is correct but Statement II is incorrect.

D

Statement I is incorrect but Statement II is correct.

Answer

Statement I is correct but Statement II is incorrect.

Explanation

Solution

S-I is correct but S-II is incorrect as o-, m- and p-nitrophenol are more acidic than phenol.
o-,p- and m-nitrophenol have different acidic strength.