Question
Question: Statement \(I:\)A molecule of ethyne is linear. Because Statement \(II:\)The carbon atoms in et...
Statement I:A molecule of ethyne is linear.
Because
Statement II:The carbon atoms in ethyne are sp hybridized.
A)True, True CE
B)True, True
C)True, False
D)False, True
E)False, False
Solution
The hybridization in ethyne is similar to the hybridization in magnesium hydride. For each carbon, the 2s orbital hybridizes with one of the 2p orbitals to form two sp hybridized orbitals. The first bond consists of sp−sp orbital overlap between the two carbons.
Complete answer:
The molecular geometry about a carbon atom in an organic molecule depends on the number of atoms bonded to the carbon.
Ethyne molecule is linear because the two carbon atoms forming the single bond in ethyne have an angle of 180 degrees between them that form a straight line. Both of these carbon atoms are sphybridized and overlap in a linear fashion.
Both the carbon atoms are triply bonded here, which means that both of them have formed 1 sigma and 2 pi bonds, which means both the C atoms have two sets of unhybridized atomic p orbitals
which undergo parallel overlap in order to give rise to the two pi bonds between the already sigma-bonded sp−hybridised C atoms.
So, the correct answer is A)True, True CE
Approximately 20% of acetylene is supplied by the industrial gases industry for oxyacetylene gas welding and cutting due to the high temperature of the flame. Acetylene is not especially toxic, but when generated from calcium carbide, it can contain toxic impurities such as traces
of phosphine and arsine, which give it a distinct garlic-like smell.
Note:
Ethyne, which is commonly called acetylene, is the simplest alkyne. Historically, it was prepared by reacting calcium carbide with water. Today, ethyne is normally prepared by the pyrolysis of methane. In this procedure, a stream of methane gas is briefly heated to 1500∘C in an airless chamber.