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Question: Statement 1: \(NO_3^​-\) and \(CO_3^{2-}\)​ are planar species. Statement 2: Each ion has three eq...

Statement 1: NO3NO_3^​- and CO32CO_3^{2-}​ are planar species.
Statement 2: Each ion has three equal bonds distributed equivalently in space.
(A) Both Statement 11 and Statement 22 are correct and Statement 22 is the correct explanation of Statement 11.
(B) Both Statement 11 and Statement 22 are correct, but Statement 22 is NOT the correct explanation of Statement 11.
(C) Statement 11 is correct, but Statement 22 is not correct.
(D) Statement 11 is not correct, but Statement 22 is correct.

Explanation

Solution

The shape of a molecule depends upon the hybridization of the molecule, and the repulsion between the bonding atoms. Hybridization is defined as the combination of atomic orbitals of similar energy to form new orbitals. A molecule will have a planar shape if it has a hybridization of sp2sp^2.

Complete step by step answer:
The NO3NO_3^- ion consists of nitrogen as the central atom, surrounded by three oxygen atoms as shown in the following diagram:

There are no lone pairs on the nitrogen atom. So, there is no lone pair-bond pair repulsion in the molecule. There are three sigma bonds in the molecule, so the hybridization in the molecule is sp2sp^2.
Now, there will be repulsion between the oxygen atoms that are surrounding the central nitrogen atom. Since the surrounding atoms are all identical, i.e., oxygen, the repulsion between the oxygen atoms will also be the same. Due to this repulsion, the oxygen atoms align themselves at an angle of 120120\circ to each other. Therefore, the ion has a trigonal planar shape.
Like NO3NO_3^- ion, CO32CO_3^{2-} ion also consists of three oxygen atoms surrounding a central carbon atom. The structure of the CO32CO_3^{2-} ion can be represented through the following diagram:

Again, in the carbonate ion, there are no lone pairs on the carbon atom, and therefore, no lone pair-bond pair repulsion in the molecule. The hybridization in the molecule is also sp2sp_2 as there are three sigma bonds.
Also, the surrounding atoms are the same as that in the nitrate ion. The three oxygen atoms will repel each other and form an angle of 120120\circ with each other to attain stability.
Therefore, in the case of both CO32CO_3^{2-} and NO3NO_3^-, the bond angle is 120120\circ. Therefore, they both are trigonal planar species, and it is also true that both the ions have three equal bonds distributed equivalently in space at angles of 120120 ^\circ each. But it is not true that because of an equivalent distribution in space, the molecules have a planar shape. The planar shape of the molecule is because the hybridization of both the molecules is sp2sp^2, and there is no lone pair-bond pair repulsion in the molecules.
Therefore, both statements 11 and 22 are correct, but statement 22 is not the correct explanation for statement 11.

So, the correct answer is Option B.

Note: Hybridization always involves only one ss- orbital and the corresponding number of pp- orbitals as per the number of sigma bonds. The sigma bonds in a molecule are the single bonds in the molecule. In the case of both NO3NO_3^- and CO32CO_3^{2-}, the number of sigma or single bonds is 33. So, the total number of orbitals including ss- and pp- should also be three. Therefore, the hybridization of both the given ions can be simply deduced to be Sp2Sp^2 (one ss- orbital and two pp- orbitals).