Solveeit Logo

Question

Chemistry Question on Bonding in Metal Carbonyls

Spin only magnetic moment of the compound Hg[Co(SCN)4]Hg[Co(SCN)_4] is

A

3\sqrt 3

B

15\sqrt {15}

C

24\sqrt {24}

D

8\sqrt {8}

Answer

15\sqrt {15}

Explanation

Solution

In Hg[Co(SCN)4],CO2+Hg[Co(SCN)_4], CO^{2+} has 3d73d^7 configuration. SCNSCN^- produces weak ligand field, no pairing of electrons in d-orbitals occurs against Hund's rule, hence :μ=3(3+2)BM=15BM\mu =\sqrt {3(3+2)}BM=\sqrt {15} BM