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Question

Chemistry Question on Electronic configuration of atoms and ions

Spin only magnetic moment is same for which of the following ions?
A. T3+
B. Cr2+
C. Mn2+
D. Fe2+
E. Se3+
Choose the most appropriate answer from the options given below

A

B and D only

B

A and E only

C

B and C only

D

A and D only

Answer

B and D only

Explanation

Solution

1. Magnetic moment is calculated as:

μ=n(n+2)BM\mu = \sqrt{n(n + 2)} \, \text{BM},

where nn is the number of unpaired electrons.

2. For Cr2+Cr^{2+} (d4d^4) and Fe2+Fe^{2+} (d6d^6), n=4n = 4. Both ions have the same spin-only magnetic moment:

μ=4(4+2)=4.90BM\mu = \sqrt{4(4 + 2)} = 4.90 \, BM.