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Question

Chemistry Question on Isomerism in Coordination Compounds

Specify the coordination number of cobalt in [Co(CN)(H2O)(en)2]2+\left[ Co ( CN )\left( H _{2} O \right)( en )_{2}\right]^{2+}

A

6

B

4

C

0

D

3

Answer

3

Explanation

Solution

Let oxidation number of Co be xx; Oxidation number of H2O=0H _{2} O =0
Oxidation number of CN=1C N=-1
Therefore [Co(CN)(H2O)(en)2]2\left[ Co ( CN )\left( H _{2} O \right)(e n)^{2}\right]^{2}
x+2(0)1=+2x1=+2=+3\therefore x +2(0)-1=+2 x-1=+2=+3
or 3 Hence, coordination number of CoCo is 33.