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Question

Chemistry Question on d -and f -Block Elements

Solution of Na2CrO4Na_2CrO_4 in water is coloured. Oxidation state of CrCr in Na2CrO4Na_2CrO_4 is +6+6.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion

B

If both assertion and reason are true and the reason is not the correct explanation of the assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Answer

If both assertion and reason are true and the reason is not the correct explanation of the assertion

Explanation

Solution

Na2CrO4Na _{2} CrO _{4} solution in water is yellow in colour, when acidified changes to orange colour (due to the formation of Cr2O22Cr _{2} O _{2}{ }^{2-} ions). Na2CrO4+H2SO4Na2Cr2O7+Na2SO4+H2ONa _{2} CrO _{4}+ H _{2} SO _{4} \longrightarrow Na _{2} Cr _{2} O _{7}+ Na _{2} SO _{4}+ H _{2} O Oxidation state : Na2CrO4Na _{2} CrO _{4} Let oxidation state of CrCr be xx. 2(+1)+x+4(2)=0x=+6\Rightarrow 2(+1)+x+4(-2)=0 \Rightarrow x=+6.