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Question: Solubility of AgCl in water , 0.01 M CaCl<sub>2</sub>, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3an...

Solubility of AgCl in water , 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3andS4 respectively then.

A

S1> S2> S3> S4

B

S1 > S3> S2> S4

C

S1> S2 = S3> S4

D

S1 > S3>S4< S2

Answer

S1 > S3> S2> S4

Explanation

Solution

AgClAg+Cl\mathrm { AgCl } \quad \mathrm { Ag } + \mathrm { Cl } ^ { - }

In CaCl2\mathrm { CaCl } _ { 2 }

CaCl2Ca+2+2Cl\mathrm { CaCl } _ { 2 } \quad \mathrm { Ca } ^ { + 2 } + 2 \mathrm { Cl } ^ { - }

Common ion effect is maximum in AgNO3

So, S1>S3>S2>S4S _ { 1 } > S _ { 3 } > S _ { 2 } > S _ { 4 }