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Question: Solid \({ NaHCO }_{ 3 }\) will be neutralized by \({ 40.0mL }\) of \({ 0.1M }\) \({ H }_{ 2 }{ SO }_...

Solid NaHCO3{ NaHCO }_{ 3 } will be neutralized by 40.0mL{ 40.0mL } of 0.1M{ 0.1M } H2SO4{ H }_{ 2 }{ SO }_{ 4 } solution. What would be the weight of solid NaHCO3{ NaHCO }_{ 3 } in a gram?
A.0.672g{ 0.672g }
B.6.07g{ 6.07g }
C.17g{ 17g }
D.20g{ 20g }

Explanation

Solution

Hint:
Neutralization reactions are the reactions where an acid and a base combine to form salt and water. Neutralization reactions are important to restore soil neutrality in the case of acidic and basic soils.

Complete step-by-step answer:
It is given that;
Volume of H2SO4{ H }_{ 2 }{ SO }_{ 4 } = 40.0mL{ 40.0mL }
Molarity of H2SO4{ H }_{ 2 }{ SO }_{ 4 } = 0.1M{ 0.1M }
The required neutralization reaction is;
2NaHCO3+H2SO4Na2SO4+2H2O+2CO2{ 2NaHCO }_{ 3 }{ +H }_{ 2 }{ SO }_{ 4 }{ \rightarrow Na }_{ 2 }{ SO }_{ 4 }{ +2H }_{ 2 }{ O+2CO }_{ 2 }
The number of moles in 2NaHCO3{ 2NaHCO }_{ 3 } and Na2SO4{ Na }_{ 2 }{ SO }_{ 4 } are 2{ 2 } and 1{ 1 } respectively.
Therefore, the molar mass of 2NaHCO3{ 2NaHCO }_{ 3 } = 168g{ 168g }
And the molar mass of Na2SO4{ Na }_{ 2 }{ SO }_{ 4 } = 98g{ 98g }
Using the formula, we can calculate the number of moles;
Number of moles of H2SO4=Molarity×Volume(inmL){ H }_{ 2 }{ SO }_{ 4 } = Molarity{ \times } Volume ( in mL )
Put the value in the above formula, we get
The number of moles of H2SO4{ H }_{ 2 }{ SO }_{ 4 } = 40.0×0.1M=0.4mol{ 40.0\times 0.1M=0.4mol }
Also, it can be written as m-moles of NaHCO3whenneutralized=4×2=8mol{ NaHCO }_{ 3 } when neutralized = { 4\times 2=8mol }
Since mol = w÷m×1000{ w\div m\times 1000 } ......... (1)
where, w = weight
m= molar mass
Now, put the values in equation (1), we get
8=w÷84×1000{ 8=w\div 84\times 1000 }
w=84×8÷1000{ w=84\times 8\div 1000 }
w = 0.672g{ 0.672g }
Hence, the weight of solid NaHCO3{ NaHCO }_{ 3 } = 0.672g{ 0.672g }
The correct option is A.

Additional Information:
They are also used in an acid-base titration, which is a very important way of determining how much of an acid/basic compound is there in a sample.
The acid spills that happen are fixed by neutralization.
This process also takes place when purifying water for drinking.

Note: The possibility to make a mistake is that two NaHCO3{ NaHCO }_{ 3 } moles give 1 mole of Na2SO4{ Na }_{ 2 }{ SO }_{ 4 } so, you have to multiply it with 2{ 2 }.