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Question: Logarithms of readings of pressure and volume for an ideal gas were plotted on a graph as shown in F...

Logarithms of readings of pressure and volume for an ideal gas were plotted on a graph as shown in Figure. By measuring the gradient, It can be shown that the gas may be

A

monoatomic and undergoing an adiabatic change

B

monoatomic and undergoing an isothermal change

C

diatomic and undergoing an adiabatic change

D

triatomic and undergoing an isothermal change

Answer

diatomic and undergoing an adiabatic change

Explanation

Solution

The plot of logP\log P vs logV\log V for an adiabatic process PVγ=constantPV^\gamma = \text{constant} has a slope of γ-\gamma. From the graph, the slope is calculated as 2.102.381.301.10=1.4\frac{2.10 - 2.38}{1.30 - 1.10} = -1.4. Thus, γ=1.4\gamma = 1.4. This value corresponds to a diatomic gas (γ=7/5\gamma = 7/5). An isothermal process has a slope of 1-1, which is not observed.