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Question

Chemistry Question on Electrochemistry

Silver is removed electrolytically from 200mL200 \,mL of a 0.1N0.1\, N solution of AgNO3AgNO _{3} by a current of 0.1A0.1\, A. How long will it take to remove half of the silver from the solution?

A

0.1 s

B

100 s

C

965 s

D

9650 s

Answer

9650 s

Explanation

Solution

MmolesAgNO3=0.1×200=20 Ag+eAgMmoles \, A g N O _{3}= 0 . 1 \times 2 0 0 = 2 0\\\ A g ^{\oplus}+ e ^{-} \rightarrow A g For50% For \, 50 \% electrolysis, 10mF10 \,mF \, is required 10mF=1t96500t=9650s\Rightarrow 10\, mF =\frac{1 t }{96500} \Rightarrow t = 9650 s