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Question: Silver (atomic weight= \(108g.mo{l^{ - 1}}\) ) has a density of \(10.5g.c{m^{ - 3}}\) . The number o...

Silver (atomic weight= 108g.mol1108g.mo{l^{ - 1}} ) has a density of 10.5g.cm310.5g.c{m^{ - 3}} . The number of silver atoms on a surface of area 1012m2{10^{ - 12}}{m^2} can be expressed in scientific notation as y×10xy \times {10^{ - x}}. The value of xx is ?

Explanation

Solution

To figure out how many atoms are there in a sample, we should first multiply the weight in grams by the (amu) atomic mass from the periodic table, then multiply by Avogadro's number: 6.02×10236.02 \times {10^{23}}.

Complete answer:
Firstly, let us look at the values that are given in the question:
Density= 10.5g.cm310.5g.c{m^{ - 3}}
Surface area= 1012m2=108cm2{10^{ - 12}}{m^2} = {10^{ - 8}}c{m^2}
10.5gm10.5gm of silver \to 1cm31c{m^3}
Now, we need to convert the gram unit to mole. The formula used is:
mole=weightMolecular.weight mole=10.5108  mole = \dfrac{{weight}}{{Molecular.weight}} \\\ mole = \dfrac{{10.5}}{{108}} \\\

We know that,
Atom of silver =density×NA = density \times {N_A}
Substituting the values,
Atom of silver= 10.5108×6.023×1023\dfrac{{10.5}}{{108}} \times 6.023 \times {10^{23}}
Now , in order to change the values from cmcm to mm, we will raise the power to 23\dfrac{2}{3}.
Hence,
Atom of silver= (10.5108×6.023×1023)23{\left( {\dfrac{{10.5}}{{108}} \times 6.023 \times {{10}^{23}}} \right)^{\dfrac{2}{3}}}
Now, the number of silver atom for 1cm21c{m^2} surface area is:
(10.5108×6.023×1023)231cm2 (10.5108×6.023×1023)23×108108cm2 =1.5×107atoms  {\left( {\dfrac{{10.5}}{{108}} \times 6.023 \times {{10}^{23}}} \right)^{\dfrac{2}{3}}} \to 1c{m^2} \\\ {\left( {\dfrac{{10.5}}{{108}} \times 6.023 \times {{10}^{23}}} \right)^{\dfrac{2}{3}}} \times {10^{ - 8}} \to {10^{ - 8}}c{m^2} \\\ = 1.5 \times {10^{ - 7}}atoms \\\
Now the scientific notation is equal to the above value. Hence, we get:
y×10x=1.5×107y \times {10^x} = 1.5 \times {10^{ - 7}}
Comparing the values we get, y=1.5y = 1.5 and x=7x = 7.
Hence, the answer is 77 .

Note:
The Avogadro constant is a proportionality element that connects the number of constituent particles in a sample to the volume of material present. The reciprocal mole is its SI unit, and it is defined as NA = 6.022×1023mol16.022 \times {10^{23}}mo{l^{ - 1}}. It is named after Amedeo Avogadro, an Italian physicist.