Question
Chemistry Question on Atomic Models
Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie wavelength associated with the electron revolving around the orbit.
Since a hydrogen atom has only one electron, according to Bohr's postulate, the angular momentum of that electron is given by: mvr =2πnh ....(1)
Where, n = 1, 2, 3, …
According to de Broglie's equation: λ=mvh
or mv = λh ....(2)
Substituting the value of 'mv' from expression (2) in expression (1):
λhr = 2πnh
or 2πr = nλ ......(3)
Since '2πr' represents the circumference of the Bohr orbit (r), it is proved by equation (3) that the circumference of the Bohr orbit of the hydrogen atom is an integral multiple of de Broglie's wavelength associated with the electron revolving around the orbit.