Question
Question: Select incorrect statement:...
Select incorrect statement:
Interstitial carbides are formed by metalloids like Si and B
SiC is called carborundum
CO and CN– both are fatal due to complex formation with Fe(III) present in blood
CO is obtained as by-product when carbon and SiO2 is used in reduction processes of phosphate rock to give phosphorus.
Interstitial carbides are formed by metalloids like Si and B
Solution
(1) Interstitial carbides are formed by transition elements and lanthanides.
(2) SiC is a covalent carbide known by the name
carborundum.
(3) CO is toxic, because it forms a complex with
haemoglobin in the blood and this complex is more stable than oxy-haemoglobin. This prevents the haemoglobin in the red blood corpuscles from carrying oxygen round the body. This causes oxygen deficiency, leading to unconsciousness and then death.
Hb—O2 + CO ⟶ Hb—CO + O2
(4) 2Ca3(PO4)2 + 6SiO2 + 10C ⟶P4 + 6CaSiO3 + 10CO.