Question
Chemistry Question on Thermodynamics terms
Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure. AB → Isothermal expansion AC → Adiabatic expansion Which of the following options is not correct ?
A
ΔSisothermal>ΔSadiabatic
B
TA = TB
C
Wisothermal>Wadiabatic
D
Tc > TA
Answer
Tc > TA
Explanation
Solution
In adiabatic expansion cooling effect will take place, TC will be less then TA. in adiabatic expansion q=0 ΔU=w Wpv<0 ΔU<0 nCvmΔT<0 ΔT<0 TC−TA<0 TC<TA