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Question

Chemistry Question on Thermodynamics terms

Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure. AB \rightarrow Isothermal expansion AC \rightarrow Adiabatic expansion Which of the following options is not correct ?

A

ΔSisothermal>ΔSadiabatic\Delta S_{isothermal} > \Delta S_{adiabatic}

B

TA_A = TB

C

Wisothermal>WadiabaticW_{isothermal} > W_{adiabatic}

D

Tc_c > TA

Answer

Tc_c > TA

Explanation

Solution

In adiabatic expansion cooling effect will take place, TCT_C will be less then TAT_A. in adiabatic expansion q=0q = 0 ΔU=w\Delta U = w Wpv<0Wpv < 0 ΔU<0\Delta U < 0 nCvmΔT<0nC_{vm} \Delta T < 0 ΔT<0\Delta T < 0 TCTA<0T_C - T_A < 0 TC<TAT_C < T_A