Question
Chemistry Question on The Lanthanoids
Reason of lanthanoid contraction is
A
negligible screening effect of 'f'-orbitals
B
increasing nuclear charge
C
decreasing nuclear charge
D
decreasing screening effect
Answer
negligible screening effect of 'f'-orbitals
Explanation
Solution
Lanthanoid contraction is the regular decrease in atomic and ionic radii of lanthanides. This is due to the imperfect shielding [or poor screening effect] of /-orbitals due to their diffused shape which unable to counterbalance the effect to the increased nuclear charge. Hence, the net result is a contraction in size of lanthanoids.