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Question

Chemistry Question on The Lanthanoids

Reason of lanthanoid contraction is

A

negligible screening effect of 'f'-orbitals

B

increasing nuclear charge

C

decreasing nuclear charge

D

decreasing screening effect

Answer

negligible screening effect of 'f'-orbitals

Explanation

Solution

Lanthanoid contraction is the regular decrease in atomic and ionic radii of lanthanides. This is due to the imperfect shielding [or poor screening effect] of /-orbitals due to their diffused shape which unable to counterbalance the effect to the increased nuclear charge. Hence, the net result is a contraction in size of lanthanoids.