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Question

Chemistry Question on Quantum Mechanical Model of Atom

Read the passage given below and answer the question The hydrogen-like species Li2+Li^{2+} is in a spherically symmetric state S1S_1 with one radial node. Upon absorbing light the ion undergoes transition to a state S2S_2. The state S2S_2 has one radial node and its energy is equal to the ground state energy of the hydrogen atom. Energy of the state S1S_1 in units of the hydrogen atom ground state energy is

A

0.750.75

B

1.501.50

C

2.252.25

D

4.504.50

Answer

2.252.25

Explanation

Solution

For S1S_1 state of Li2+Li^{2+}, n=2n = 2 and Z=3Z = 3. \therefore Energy of the state S1S_1 in the units of hydrogen atom ground state energy is : E=EH×Z2n2E=E_{H}\times\frac{Z^{2}}{n^{2}} EH×3222E_{H}\times\frac{3^{2}}{2^{2}} =94EH=\frac{9}{4}E_{H} =2.25×EH=2.25\times E_{H}