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Question

Chemistry Question on Ammonia

Reaction of [Co(H2O)6]2+ with excess ammonia and in the presence of oxygen results into a diamagnetic product. Number of electrons present in t2g-orbitals of the product is _______

Answer

[Co(H2O)6]2+O2NH3[Co(NH3)6]3++e\mathrm{[Co(H_2O)_6]^{2+} \overset{\text{NH}_3}{\underset{\text{O}_2}{\rightarrow}} [Co(NH_3)_6]^{3+} + e^-}
Co3+3d6Co^{3+} → 3d^6
NH3 is a strong field ligand
3d6t2g6eg03d^6 → t^{6}_{2g} eg^0
Total Number of electrons : 6