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Question: Pure water is added into the following solutions causing a 10% increase in volume of each. The great...

Pure water is added into the following solutions causing a 10% increase in volume of each. The greatest % change in pH would be observed in which case (1), (2), (3) or (4) ?

A

0.1 M NaHCO3

B

0.2 M NaOH

C

0.3 M NH3 – 0.2 M NH4+system

D

0.4 M CH3COONH4

Answer

0.2 M NaOH

Explanation

Solution

(1) pH of NaHCO3 is independent of dilution.

(3) pH of buffer solution is approximately remains constant with dilution.

(4) pH of salt of WA & WB is independent of dilution.