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Question: Pure ethanol is difficult to prepare and therefore expensive, \[95\% \] (v/v) ethanol is much cheape...

Pure ethanol is difficult to prepare and therefore expensive, 95%95\% (v/v) ethanol is much cheaper. Consequently, 95%95\% ethanol is generally used in the preparation of dilute water solutions of ethanol. It has been found that 70%70\% (v/v) ethanol concentration is the most effective for preoperative skin disinfection. How much 95%95\% ethanol would be needed to produce a 2.5 L2.5{\text{ }}Lsolution of 70%70\% ethanol?

Explanation

Solution

95%95\% (v/v) of ethanol means 95ml95mlof ethanol diluted in 100ml100mlof water. Same goes for 70%70\% (v/v) ethanol, 70ml70mlof ethanol diluted in 100ml100mlof water. Using this, calculate the amount required. It is given (v/v) ratio so ethanol will be taken in milliliters and not in gm.

Complete answer:
We need to find how much of 95%95\% ethanol is required to prepare 2.5 L2.5{\text{ }}Lsolution of 70%70\% ethanol
We know that 70%70\% of ethanol means 70ml70ml of ethanol diluted in 100ml100mlof water
This can be written as:
100ml70ml100ml\xrightarrow{{}}70ml
1ml70100ml\Rightarrow 1ml\xrightarrow{{}}\dfrac{{70}}{{100}}ml
We need 2.5 L2.5{\text{ }}Lof solution and so we will convert milliliters to liters.
So, 1 L70100×1000ml \Rightarrow 1{\text{ L}}\xrightarrow{{}}\dfrac{{70}}{{100}} \times 1000ml (as1L=1000ml1L = 1000ml)
2.5 L70100×1000×2.5ml\Rightarrow 2.5{\text{ L}}\xrightarrow{{}}\dfrac{{70}}{{100}} \times 1000 \times 2.5ml
70×25ml\Rightarrow 70 \times 25ml
Thus, by this we found out that 2.5 L2.5{\text{ }}Lof solution contains 70×25ml70 \times 25mlof 70%70\% ethanol
Now we need to calculate the quantity of 95%95\% (v/v) ethanol that is required for preparing 2.5 L2.5{\text{ }}Lsolution of 70%70\% ethanol. We will calculate it in the same manner we did for 70%70\% ethanol.
95%95\% Of ethanol means 95ml95mlof ethanol diluted in 100ml100mlof water.
So 95ml100ml95ml\xrightarrow{{}}100ml
1ml10095ml\Rightarrow 1ml\xrightarrow{{}}\dfrac{{100}}{{95}}ml
70×25ml10095×70×25ml\Rightarrow 70 \times 25ml\xrightarrow{{}}\dfrac{{100}}{{95}} \times 70 \times 25ml
1842.10ml\Rightarrow 1842.10ml
Therefore 1842.10ml1842.10mlof 95%95\% ethanol is required for the preparation of 2.5 L2.5{\text{ }}Lsolution of 70%70\% ethanol. This means that 1.84210 L1.84210{\text{ L}}of 95%95\% ethanol is required to prepare 2.5 L2.5{\text{ }}Lsolution of 70%70\% ethanol.

Note:
70%70\% or 95%95\% of ethanol is given in (v/v) i.e. volume by volume ratio. Sometimes it might be given (w/v) this is weight by volume ratio. This means that in case of 70%70\% of ethanol, 70gm70gmof ethanol is diluted in 100ml100mlof water. And for 95%95\% of ethanol 95gm95gmof ethanol diluted in 100ml100mlof water.