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Question

Chemistry Question on Chemical Reactions

Products for the below reaction are:
CCH3CH3CH3O

A

B

C

Answer

Explanation

Solution

The given reaction involves the cleavage of the ether bond using HI\text{HI}. The major products are formed through the nucleophilic substitution of HI\text{HI} on the ether linkage. The reaction mechanism proceeds as follows:

Protonation of the ether oxygen atom by HI\text{HI}, resulting in the formation of an oxonium ion intermediate.
Cleavage of the C–O\text{C–O} bond forms cyclohexanol and a tertiary carbocation ((CH3)3C+(\text{CH}_3)_3\text{C}^+).
The tertiary carbocation rapidly reacts with I\text{I}^- to form (CH3)3C–I(\text{CH}_3)_3\text{C–I} as the final product.
The correct option is (A) :