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Question

Chemistry Question on Buffer Solutions

pKapK_a of CH3COOHCH_3COOH is 4.74. The pH of 0.01 M CH3COONaCH_3COONa is

A

4.74

B

8.37

C

9.48

D

None of these

Answer

8.37

Explanation

Solution

CH3COONaCH_{3}COONa is a salt of a weak acid and strong base PH=7+12[PKa+logC]\therefore PH =7+\frac{1}{2}[PK_{a}+log\,C] =7+12[4.74+log0.01]=7+\frac{1}{2} [4.74+log\,0.01] =7+12[4.742]=7+\frac{1}{2} [4.74-2] =8.37=8.37