Question
Chemistry Question on packing efficiency
Percentage of free space in body centred cubic (bcc) unit cell is
A
0.3
B
0.32
C
0.34
D
0.28
Answer
0.32
Explanation
Solution
In bcc unit cell, the number of atoms = 2 Thus, volume of atoms in unit cell (v)=2×34πr3 For bcc structure(r)=43a (V)=2×34π(43a)3=83πa3 Volume of unit cell (V)=a3 Percentage of volume occupied by unit cell =VolumeofunitcellVolumeoftheatomsinunitcell =a383πa3×100=83π×100=68% Hence, the free space in bcc unit cell = 100 -68=32%.