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Question

Chemistry Question on packing efficiency

Percentage of free space in body centred cubic (bcc) unit cell is

A

0.3

B

0.32

C

0.34

D

0.28

Answer

0.32

Explanation

Solution

In bcc unit cell, the number of atoms = 2 Thus, volume of atoms in unit cell (v)=2×43πr3(v)=2\times\frac{4}{3}\pi r^3 For bcc structure(r)=34a(r)=\frac{\sqrt{}3}{4}a (V)=2×43π(34a)3=38πa3(V)=2\times\frac{4}{3}\pi\Bigg(\frac{\sqrt{3}}{4}a\Bigg)^3=\frac{\sqrt{3}}{8}\pi a^3 Volume of unit cell (V)=a3(V)=a^3 Percentage of volume occupied by unit cell =VolumeoftheatomsinunitcellVolumeofunitcell=\frac{Volume \, of\, the\, atoms \, in\, unit\, cell}{Volume \, of \,unit\, cell} =38πa3a3×100=38π×100=68%=\frac{\frac{\sqrt{3}}{8}\pi a^3}{a^3}\times100=\frac{\sqrt{3}}{8}\pi \times 100=68\% Hence, the free space in bcc unit cell = 100 -68=32%.