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Question

Chemistry Question on Thermodynamics

P-V diagram of a diatomic gas is a straight line passing through origin. The molar heat capacity of the gas in the process will be (where RR is universal gas constant)

A

4R4R

B

3R3R

C

43R\frac{4}{3}R

D

2.5R2.5R

Answer

3R3R

Explanation

Solution

As PVP-V diagram is a straight line passing through origin, therefore, P??P ?? or PV1=PV^{-1} = constant In the process, PVx=PV^x = constant, molar heat capacity is given by C=Rγ1+R1xC=\frac{R}{\gamma-1}+\frac{R}{1-x} where x=1x = -1 here and ?=1.4? = 1.4 for diatomic gas. C=R1.41+R1(1)=52R+R2\therefore C=\frac{R}{1.4-1}+\frac{R}{1-\left(-1\right)}=\frac{5}{2}R+\frac{R}{2} C=3RC=3\,R