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Question: Oxygen molecule is paramagnetic in nature. What is the paramagnetic content in terms of magnetic mom...

Oxygen molecule is paramagnetic in nature. What is the paramagnetic content in terms of magnetic moment in O2O_{2}^{-}?

A

1.7321.732

B

3

C

1.51.5

D

2.52.5

Answer

1.7321.732

Explanation

Solution

: O2:(σ1s2)(σ1s2)(σ2s2)(σ2s2)(σ2pz2)O_{2}^{-}:(\sigma 1s^{2})(\sigma*1s^{2})(\sigma 2s^{2})(\sigma*2s^{2})(\sigma 2p_{z}^{2})

(π2px2=π2py2)(π2px2=π2py1)(\pi 2p_{x}^{2} = \pi 2p_{y}^{2})(\pi*2p_{x}^{2} = \pi*2p_{y}^{1})

O2O_{2}^{-}has 1 unpaired electron.

μ=n(n+2)=1(1+2)=3=1.732B.M.\mu = \sqrt{n(n + 2)} = \sqrt{1(1 + 2)} = \sqrt{3} = 1.732B.M.