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Question

Chemistry Question on Colligative Properties

Osmotic pressure of urea solution at 10^\circC is 500 mm. Osmotic pressure of the solution becomes 1053 mm when it is diluted and the temperature israised to 25 ^\circC. The extent of dilution is

A

6 times

B

5 times

C

7 times

D

4 time

Answer

5 times

Explanation

Solution

π1π2=n1RT1/V1n2RT2/V2\frac{\pi_1}{\pi_2} = \frac{n_1 RT_1 /V_1}{n_2 RT_2 /V_2} or 500105.3=283/V1298/V2\frac{500}{105.3} = \frac{283 /V_1}{298/V_2} \therefore V2/V1V_2 /V_1 = 5