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Question

Chemistry Question on Alkanes

One of the following cannot be prepared by Kolbe's electrolytic process ?

A

C2H2C_2H_2

B

C2H6C_2H_6

C

CH4CH_4

D

C2H4C_2H_4

Answer

CH4CH_4

Explanation

Solution

RCOONa+H2ORCOONa + H_2O >[Electrolysis]RR+CO2(Higher alkane)+H2+NaOH {->[\text{Electrolysis}]} \underset{(\text{Higher alkane})}{R-R + CO_2} + H_2 + NaOH