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Question

Chemistry Question on Redox reactions

One mole of hydrazine (N2H4)(N_2H_4) loses 1010 moles of electrons in a reaction to form a new compound XX. Assuming that all the nitrogen atoms in hydrazine appear in the new compound, what is the oxidation state of nitrogen in XX ? (Note: There is no change in the oxidation state of hydrogen in the reaction)

A

-1

B

-3

C

3

D

5

Answer

3

Explanation

Solution

Given, 1mol1\, mol of H2NNH2H _{2} N - NH _{2} (hydrazine), it loses 10 moles of electrons to form a new compound that contains both the N-atoms with same oxidation number means: N2H410e+XN _{2} H _{4} \longrightarrow 10 e^{-}+X (product) (Oxidation number of NN -atom in N2H4=2N _{2} H _{4}=-2 ) \because Oxidation number of both the NN - atoms are same. New total oxidation number of new compound (X)atoms) =410+x=0=4-10+x=0 (due to 4 H- atoms) x=+6\therefore x=+6 \therefore Each NN -atom has oxidation state =+3=+3 N2H4(2)X\underset{(-2)}{ N _{2} H _{4}} \longrightarrow X Number of electrons lost per NN - atom =5=5 \therefore New oxidation state of NN in XX =2+5+x=0=-2+5+x=0 x=+3x=+3