Question
Question: One mole of helium is heated at \[{0^ \circ }{\text{C}}\] and constant pressure. How much heat is re...
One mole of helium is heated at 0∘C and constant pressure. How much heat is required to increase the four-fold?
(A) 4095cal.
(B) 5500cal.
(C) 6000cal.
(D) 6500cal.
Solution
Hint In this question we will use the concept of the Charles law. First, we will calculate the change in temperature by using the Charles law which means that volume of the gas is directly proportional at constant pressure.
Complete step by step answer
In this question, we are given that one mole of helium is heated at constant pressure and the temperature is 0∘C.
Let represent the mole by n. One mole is,
n=1
One should know the Charles law; Charles law says that volume of an ideal gas is directly proportional to the absolute temperature to constant pressure.
When the pressure is constant,
⇒T1V1=T2V2
Let us assume ΔT is the change in temperature, Tf is the final temperature, and Ti is the initial temperature.
We are given
Ti=273k
So, for fourfold increase in the temperature, the temperature is,
Ti=4×273k
Now we will simplify the above expression.
⇒Ti=1092k
Now we will calculate the change in temperature,
ΔT=Tf−Ti
Now we substitute the value of change in temperature,
⇒ΔT=1092−273
Now we will simplify the above expression.
⇒ΔT=819k
As we know the valency of helium is 2, so the helium is the diatomic molecule.
⇒CV=γ−1R
Now we substitute the value
⇒CV=35−1R
Further solving, we get
CV=35−3R
⇒CV=23R
Now we will calculate the Cp,
⇒CP=R+CV
For the monatomic gas, the value of Cp is 25R.
Now to calculate the change in heat using formula,
ΔQ=ncPΔT
Now we will substitute the values, where, ΔQ is the change in heat.
⇒ΔQ=1×25×2×819
Further solving, we get
∴ΔQ=4095cal
Therefore, the option (A) is correct.
Note
In this question, do not forget to write the change in heat Si unit. The amount of heat is measured in calories. The calorie is the amount of the energy required for one degree Celsius to raise one gram of water.