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Question: One mole of helium is heated at \[{0^ \circ }{\text{C}}\] and constant pressure. How much heat is re...

One mole of helium is heated at 0C{0^ \circ }{\text{C}} and constant pressure. How much heat is required to increase the four-fold?
(A) 4095  cal4095\;{\text{cal}}.
(B) 5500  cal5500\;{\text{cal}}.
(C) 6000  cal6000\;{\text{cal}}.
(D) 6500  cal6500\;{\text{cal}}.

Explanation

Solution

Hint In this question we will use the concept of the Charles law. First, we will calculate the change in temperature by using the Charles law which means that volume of the gas is directly proportional at constant pressure.

Complete step by step answer
In this question, we are given that one mole of helium is heated at constant pressure and the temperature is 0C{0^ \circ }{\text{C}}.
Let represent the mole by nn. One mole is,
n=1n = 1
One should know the Charles law; Charles law says that volume of an ideal gas is directly proportional to the absolute temperature to constant pressure.
When the pressure is constant,
V1T1=V2T2\Rightarrow \dfrac{{{V_1}}}{{{T_1}}} = \dfrac{{{V_2}}}{{{T_2}}}
Let us assume ΔT\Delta T is the change in temperature, Tf{T_f} is the final temperature, and Ti{T_i} is the initial temperature.
We are given
Ti=273  k{T_i} = 273\;{\text{k}}
So, for fourfold increase in the temperature, the temperature is,
Ti=4×273  k{T_i} = 4 \times 273\;{\text{k}}
Now we will simplify the above expression.
Ti=1092  k\Rightarrow {T_i} = 1092\;{\text{k}}
Now we will calculate the change in temperature,
ΔT=TfTi\Delta T = {T_f} - {T_i}
Now we substitute the value of change in temperature,
ΔT=1092273\Rightarrow \Delta T = 1092 - 273
Now we will simplify the above expression.
ΔT=819  k\Rightarrow \Delta T = 819\;{\text{k}}
As we know the valency of helium is 22, so the helium is the diatomic molecule.
CV=Rγ1\Rightarrow {C_V} = \dfrac{R}{{\gamma - 1}}
Now we substitute the value
CV=R531\Rightarrow {C_V} = \dfrac{R}{{\dfrac{5}{3} - 1}}
Further solving, we get
CV=R533{C_V} = \dfrac{R}{{\dfrac{{5 - 3}}{3}}}
CV=32R\Rightarrow {C_V} = \dfrac{3}{2}R
Now we will calculate the Cp{C_p},
CP=R+CV\Rightarrow {C_P} = R + {C_V}
For the monatomic gas, the value of Cp{C_p} is 52R\dfrac{5}{2}R.
Now to calculate the change in heat using formula,
ΔQ=ncPΔT\Delta Q = n{c_P}\Delta T
Now we will substitute the values, where, ΔQ\Delta Q is the change in heat.
ΔQ=1×52×2×819\Rightarrow \Delta Q = 1 \times \dfrac{5}{2} \times 2 \times 819
Further solving, we get
ΔQ=4095  cal\therefore \Delta Q = 4095\;{\text{cal}}

Therefore, the option (A) is correct.

Note
In this question, do not forget to write the change in heat Si unit. The amount of heat is measured in calories. The calorie is the amount of the energy required for one degree Celsius to raise one gram of water.